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Even if you can't hear the difference, there is one very good reason to prefer flacs over any bitrate of mp3 (or any other lossy format) it can be transcoded to any other format for maximum quality of the target format. Transcoding from one lossy format to another is a bad thing, if you've got 192k mp3s or 320k or whatever ALL you have is the mp3s. If you've got flacs then you can convert to any format you want, 128k mp3 for limited storage on my phone or.ogg or any other format du jour. I originally had my entire music collection in 128k mp3, lost or gave away the cds.
I've since scrapped the lot and re-acquired everything as flacs and now know that I can even produce a bit identical copy of the original cds if I ever want to. Whatever future formats get produced I know I can easily convert my music collection to it should I ever have the need • • • • •. I am 100% sure that I can hear the difference. However, it would be hard to tell the difference if I compared a flac and 320kbs mp3 of just an acoustic guitar playing. It's only when there are a lot of different sounds with different frequencies.
The sound is much more pure and you can easily distinguish each element and instrument. I almost always notice sounds that I didn't know was there before when I hear the lossless for the first time. For mp3 it's more like everything gets mixed up in a big mess and all sounds overlapping each other. I'm no expert, but maybe it has to do with the fact that I haven't reached the age of 30 yet. I know a lot of people over that age can't hear high frequency sounds. It's just an accepted fact that in most cases, the sounds included that contribute data in > 192 kbps music are those that are above the frequency that can be heard by the average human ear(given that the 192 kbps track was properly encoded). You can hear more sounds with high end equipment, but still none above certain frequencies.
I believe that there are certainly reasons to keep lossless copies of music, however. It is important to be able to transcode it to lower file sizes later without lossy-lossy transcode data loss. However, when someone claims to hear the difference between lossless audio and, say, MP3s at 320 Kbps, I would challenge them to take a test so that they might get a reality check.