A series of new, dicationic platinum(II) CNC pincer complexes were prepared and characterized by NMR and X-ray diffraction analysis. Oxidative addition of methyl iodide and iodine yielded the mostly unstable platinum(IV) complexes, which readily underwent reductive elimination to yield the platinum(II) precursors. Nonetheless, a platinum(IV) iodide adduct was isolated and was characterized by X-ray diffraction analysis. Additionally, a platinum(II) ethylene complex was isolated and found to be a moderately active yet highly selective catalyst in the co-dimerization of 2-methyl-2-butene with ethylene.

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Aug 15, 2011  Baker v. APPEAL from the Circuit Court of the United States for the Southern District of Ohio. The facts are stated in the opinion of the court. Download as PDF; Printable version; In other languages. This page was last edited on 15 August 2011, at 00:04.